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Supramolecular polymers have attracted lots of interests from the field of supramolecular chemistry and polymer chemistry.[1] This poster is aimed to report a new method of controllable supramolecular polymerization.[2] In this work, two strategies, self-sorting and positive cooperativity, are jointly utilized.A bifunctional monomer bearing phenylene (Phen)and naphthalene (Naph) units was prepared.