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To design and synthesize functional molecules that can self-assemble into ordered superstructure with tunable properties by various non-covalent interactions continues to be a significant and challenging endeavour.Benzene-1,3,5-tricarboxamide (BTA), as a modifiable core widely used in supramolecular systems, exhibits one-dimensional, micrometer-sized superstructure stabilized by threefold H-bonding.