Corrosion Behavior and Hardness of Al-M (M: Mo, Si, Ti, Cr) Alloys

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The corrosion behavior of Al-5 at.% Cr,Al-5 at.% Si,Al-5 at.% Mo and Al-5 at.% Ti produced via casting and Al-5 at.% Cr produced by high-energy ball milling and subsequent consolidation by cold pressing was studied using potentiodynamic polarization and surface analysis following constant immersion tests.Alloys were characterized using a scanning electron microscope coupled with the energy-dispersive X-ray spectroscopy and X-ray diffraction analysis.Hardness,a representative of the strength,was also measured.The alloys produced by casting contained coarse intermetallics and therefore exhibited poor corrosion resistance.Al-5 at.% Cr alloy produced by high-energy ball milling exhibited a significantly improved corrosion resistance and hardness,which was attributed to the grain refinement to nanoscale and extended solid solubility of Cr in Al.The study indicated that the high-energy ball milling was capable of producing Al alloys with improved corrosion behavior and hardness.
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