【摘 要】
:
Cd2+ and Pb2+ are regarded to be the toxic metallic pollutants,which can be found in aquatic products due to the accumulations in aquatic environment.Consum
【机 构】
:
KeyLaboratoryofCoastalEnvironmentalProcessesandEcologicalRemediation,YantaiInstituteofCoastalZoneRes
【出 处】
:
2016年分析化学前沿国际研讨会及中美分析化学研讨会
论文部分内容阅读
Cd2+ and Pb2+ are regarded to be the toxic metallic pollutants,which can be found in aquatic products due to the accumulations in aquatic environment.Consumption of the aquatic products with high concentrations of these elements would damage the human health.Therefore,it is necessary to develop efficient methods to detect Cd2+ and Pb2+ in aquatic products.Inductively coupled plasma mass spectrometry(ICP-MS),as a powerful technique,is widely used for the determination of heavy metal ions.However,it is rather expensive,time-consuming and not suitable for on-site analysis.Potentiometry with ion-selective electrodes(ISEs)is a very promising method for trace heavy metal level analysis,owing to its advantages such as low cost,simple analytical procedure and fast response [1-4].In this paper,we developed a screen-printed detection system based on solid-contact ion-selective indicator electrode and liquid-junction-free reference electrode.The screen-printed electrodes are fabricated with conductive carbon paste as working electrodes and silver chloride paste as reference electrodes.For the construction of the solid-contact ion-selective indictor electrodes,octadecylamine-functionalized graphene is used as solid contact to improve the stability of the electrodes.The proposed electrodes show stable Nernstian characteristics within the concentration range of 1.0×10-6 – 1.0 ×10-3 M.
其他文献
α-Ketoglutarate(α-KG)is a important intermediate in tricarboxylic acid cycle,and is one of the major precursors for the synthesis of most biochemical subs
For electrochemical biosensor fabrication,sensitivity and selectivity are two key parameters which are mainly determined by the properties of electrode mate
Since Clack fabricated the first biosensor in the year 1962,various novel biosensors have been developed in lab for the detections of different physiologica
Self-powered electrochemical biosensors based on enzymatic biofuel cells is a kind of novel electrochemical biosensors,which combines the advantages of the
Nanozymes are nanomaterials with enzyme-like characteristics.They are advantageous over natural enzymes and conventional artificial enzymes in several aspec
With the features of micro-scale,quick mass transfer and accurate fluid control,microfluidics has become an important platform for generation of various fun
Prussian blue(PB)and its analogues,have attracted growing interest on account of their interesting properties like electrochromicity and ion-exchange select
Metallo phthalocyanines(MPcs),synthetic analogues of porphyrin,are a kind of π-electron macrocyclic conjugated system.Besides,owing to their strong absorpt
A cascade linkage-cleavage switch-on system triggered by cupric ion was established.The substrate strand was labeled with a fluorescence and a corresponding
5-hydroxymethylcytosine(5hmC)is a recently discovered epigenetic modification which is widespread in many cell types and tissues.The dynamic variation of ab