Access to the spirooxindoles by Michael addition/hemiketalization/Fridel-Crafts reaction of α-Hydrox

来源 :中国化学会全国第十二届有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户:chaba
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Spirooxindoles derivatives are one of the most common skeletons found in natural products.[1] Beacause of their unique structure property that two rings joined at a single carbon,[2] and their extensive array of biological activities and pharmacological properties[3],the synthesis of this kind of compounds has been long-standing challenge in organic chemistry,and considerable effort has been devoted to developing efficient and selective synthetic methods to access substituted spirooxindoles.[4] Herein,we report an efficient method through the Michael addition/Friedel-Crafts reaction of α-hydroxyacetophenone to β,γ-Unsaturated α-ketoamides for the synthesis of spirooxindoles.
其他文献
  Allenoate has received significant interests in organic synthesis due to its facile preparation and versatile reactivity.1 For instance,the nucleophilic add
会议
  β-Aryl carbonyl compounds have drawn much attention owing to the prevalence of this fundamental building blocks in pharmaceuticals and biologically active
会议
  The 1,3-dipolar cycloaddition reaction of azomethine ylides with alkenes is one of the most extensively studied organic reactions.Traditionally,the azomethi
会议
  Palladium-catalyzed coupling reactions is now establish as a captivating branch of organic chemistry for the construction of both carbon-carbon and/or carbo
会议
  Aryl sulfides are versatile building blocks for synthesis of organic molecules of higher complexity.These potential scaffolds are frequently found in natura
会议
  2,3-Dihydrofurans are important functionalized building blocks of natural and unnatural products because of their various biological activities,[1] sush as
会议
  Remarkable developments have been made on the synthesis of imidazo[1,2-α]pyridine derivatives,[1] making a wide range of drugs,including alpidem,olprinone,
会议
  Coumarin derivatives are very important class of heterocycles distributed in nature exhibiting diverse and functional biological activities.Additionally,tri
会议
  Transition metal-catalyzed cascade transformations of alkynols have recently attracted extensive interest because they allow highly efficient synthesis of o
会议
  β-Enaminones and β-enamino esters,which combine the nucleophilic enamine and the electrophilic enone(ester)moieties into one molecule,represent important
会议