Preparation of new sunscreen materials Ce_(1-x)Zn_xO_(2-x) via solid-state reaction at room temperat

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Superfine cerium-zinc oxides Ce_(1-x)Zn_xO_(2-x) with x = 0, 0.1, 0.3, 0.5, and 1.0 were obtained by grinding Ce(SO_4)_2·4H_2O,ZnSO_4·7H_2O and NH_4HCO_3 under the condition of surfactant PEG-400 being present at room temperature, washing the mixture with water to remove soluble inorganic salts, drying at 80℃, and calcining. The precursor and its calcined samples were characterized using thermogravimetry and differential thermal analyses (TG/DTA), UV-vis absorption spectroscopy, X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). The results showed that superfine Ce_(1-x)Zn_xO_(2-x) behaved as an excellent UV-shielding material. The ZnO-doped CeO_2 can facilitate the formation of crystalline state CeO_2. The catalytic ability of products used in air oxidation of castor oil was investigated. The results showed that the catalytic abilities of products decreased with increasing zinc amount.
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