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作者曾报道过在低分子范围采用气相渗透计(VPO),依据VPO直接测量体系不挥发溶质质点数的原理,推导出一个实用的公式,建立了测量电荷转移平衡常数(K_(ct))的新方法。后来,作者试图将此方法扩展到聚合物为给体的体系。现简报如下: 对于写成下式的反应:
The author has reported the principle of VPO in the low molecular weight range and the direct measurement of non-volatile solute mass points in the system based on VPO. A practical formula was deduced to establish a method to measure the charge transfer equilibrium constant (K ct) new method. Later, the author tried to extend this method to polymer-donor systems. The briefing is as follows: For the reaction written as: