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A novel complex [Zn(FcCOO)2(2,2’-bipy)(H2O)]2·H2O (Fc = (η5-C5H5)Fe(η5-C5H4), 2,2’-bipy = 2,2’-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray diffraction. It crystallizes in monoclinic system, space group P21/c with a = 6.8187(4), b = 21.7155(13), c = 19.7411(12) A, α = 90, β = 97.7420(10), γ = 90o, C64H58Fe4Zn2N4O11, Mr = 1413.28, V = 2896.4(3) A3, Dc = 1.620 g/cm3, Z = 2, F(000) = 1444, μ(MoKα) = 1.857 mm-1, R = 0.0523 and wR = 0.0982 for 3219 observed reflections (I > 2σ(I)). Structural analysis shows that the zinc atom is coordinated with three oxygen atoms from two ferrocenemonocarboxylates and one water molecule together with two nitrogen atoms from 2,2’-bipyridine, giving a distorted square-pyramidal coordination geometry. The complex molecules are linked to form an infinite one-dimensional chain by both intermolecular hydrogen bonds and π-π stacking interactions of the bipyridine rings.
A novel complex [Zn (FcCOO) 2 (2,2’-bipy) (H2O)] 2 · H 2 O (Fc = η 5 -C 5 H 5) Fe (η 5 -C 5 H 4) -bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray diffraction. It crystallizes in monoclinic system, space group P21 / c with a = 6.8187 (4), b = 21.7155 (13), c = 19.7411 ) A, α = 90, β = 97.7420 (10), γ = 90o, C64H58Fe4Zn2N4O11, Mr = 1413.28, V = 2896.4 (3) A3, Dc = 1.620 g / cm3, Structural analysis shows that the zinc atom is coordinated with three oxygen atoms from two ferrocenemonocarboxylates and one water molecule (I> 2σ (I)). μ (MoKα) = 1.857 mm -1, R = 0.0523 and wR = 0.0982 for 3219 observed reflections together with two nitrogen atoms from 2,2’-bipyridine, giving a distorted square-pyramidal coordination geometry. The complex molecules are linked to form an infinite one-dimensional chain by both intermolecular hydrogen bonds and π-π stacking interactions of the bipyridine rings .