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本文测定了一种新型三核钴簇合物(Co_3(bdt)_3(PBu_3)_3]的~1H NMR谱,对谱线作了归属,并和计算机模拟谱进行了比较。本文还讨论了簇合物的分子结构与它的磁性及电子结构之间的关系,并确认它在二氯甲烷溶液中仍保留着固态结构,钴原子之间存在着强烈的反铁磁偶合作用。
In this paper, the ~ 1H NMR spectra of a novel trinuclear cobalt cluster (Co_3 (bdt) _3 (PBu_3) _3] have been determined and assigned to the spectra, and compared with the computer simulation spectra The relationship between the molecular structure of the compound and its magnetic and electronic structure and confirmed that it still retains the solid structure in the dichloromethane solution, there is a strong anti-ferromagnetic coupling between cobalt atoms.