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The partial oxidation of methane (POM) to syngas over Ni/ γ Al 2O 3 catalyst has been investigated in a fluidized bed reactor. The results showed that the isothermal operation could be achieved, and CH 4 conversion and H 2 selectivity near thermodynamic equilibrium could be obtained. It was indicated that the coke deposited on the catalyst could be reduced by using a fluidized bed reactor. The CH 4 conversion as well as CO and H 2 selectivity kept almost constantly at above 92% with time on stream, no phase transformation took place on the support, and the catalyst had no remarkable Ni loss during the reaction for 100 h.
The partial oxidation of methane (POM) to syngas over Ni / γ Al 2 O 3 catalyst has been investigated in a fluidized bed reactor. The results showed that the isothermal operation could be achieved, and CH 4 conversion and H 2 selectivity near thermodynamic equilibrium could It was indicated that the coke deposited on the catalyst could be reduced by using a fluidized bed reactor. The CH 4 conversion as well as CO and H 2 was kept as 92% with time on stream, no phase transformation took place on the support, and the catalyst had no remarkable Ni loss during the reaction for 100 h.