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Two-dimensional (2D) WS2 offers great prospects for assembling next-generation optoelectronic and electronic devices due to its thickness-dependent optical and electronic properties.However,layer-number-controlled growth of WS2 is still a challenge up to now.This work presents controlled growth of bilayer WS2 triangular flakes by carbon-nanoparticle-assisted chemical vapor deposition (CVD) process.The growth mechanism is also proposed.In addition,the field effect transistors (FETs) based on monolayer and bilayer WS2 are also fabricated and investigated.The bilayer FET displays a mobility of 34 cm2·V-1·s-1,much higher than that of the monolayer FET.The high figures of merit make bilayer WS2 a promising candidate in high-performance electronics and optoelectronics.