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硫醇类的乙腈溶液在 Fe( ) (如无水 F e Cl3和 Na 催化下 ,于室温搅拌 10～ 40 min,迅速、高效地空气氧化偶联成相应的二硫化合物。 10例收率 96%～ 99%。硫醇在Fe()/Na催化下空气氧化成二硫化合物@吴雪松
Thiols in acetonitrile were rapidly and efficiently oxidized by air in the presence of Fe () (such as anhydrous F e Cl3 and Na for 10-40 min at room temperature for coupling to the corresponding disulfide compounds.) 10 % ~ 99%. Air oxidation of mercaptan to disulfide catalyzed by Fe () / Na @ Wu Xuesong