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本文以β-环糊精为主体,研究了它对2,4-二硝基苯酚、对氯苯酚和2,4-二氯苯酚的包络特性,作出了相应的包络特性曲线,探讨了浓度、pH 值对包络特性的影响。结果表明:β-环糊精对2,4-二硝基苯酚、对氯苯酚和2,4-二氯苯酚的包络物组成均为1∶1,包结常数分别为1.0×105、2.8×102、2.5×102,浓度和pH 值对包络特性有显著影响。
In this paper, β-cyclodextrin as the main body, its 2,4-dinitrophenol, p-chlorophenol and 2,4-dichlorophenol characteristics of the envelope, the corresponding envelope characteristics curve, discussed Effect of concentration and pH on the enveloping properties. The results showed that the inclusion complex of β-cyclodextrin for 2,4-dinitrophenol, p-chlorophenol and 2,4-dichlorophenol was 1: 1 and the inclusion constants were 1.0 × 105 , 2.8 × 102,2.5 × 102, the concentration and pH value of the envelope characteristics have a significant impact.