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A new molecular conductor (PyH)[Ni(dmit)2]2 (dmit = 4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for (PyH)[Ni(dmit)2]2: C17H6NNi2S20; triclinic system; P-1 space group; a = 5.9227 (4) , b =8.2279 (6), c = 16.7535 (9) A, a = 90.233 (5) , 0 = 92.107 (6) , y= 104.654 (6) ; V= 789.25 (9) A3; Z = 1; Dc = 2.068 g/cm3; F (000) = 491. The conductivity at one direction on (001) plane at room temperature was measured to be 0.13 ii^-cmf1. The resistivity-temperature curve in the temperature range of 90-290 K shows that this compound behaves as a semiconductor.
A new molecular conductor (PyH) [Ni (dmit) 2] 2 (dmit = 4, 5-dimercapto- 1, 3-dithiole- 2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for A = 5.9227 (4), b = 8.2279 (6), c = 16.7535 (9) A, a = 90.233 (5), 0 = 92.107 (6), y = 104.654 (6); V = 789.25 (9) A3; Z = 1; Dc = 2.068 g / cm3; F (000) = 491. The conductivity at one direction on (001) plane at room temperature was measured to be 0.13 ii ^ -cmf1. The resistivity-temperature curve in the temperature range of 90-290 K shows that this compound behaves as a semiconductor.