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The reactions of 18 crown 6 with each of K 2(M=Zn, Hg; mnt=1,2 dicyanoethene 1,2 dithiolate, C 2S 2(CN) 2- 2) were studied and novel complexes [K(18 C 6)] 2[Zn(mnt) 2](1) and [K(18 C 6)] 2[Hg(mnt) 2](2) were characterized by elemental analysis, IR spectrum and X ray diffraction analysis. Complex 1 displays a one dimensional chain of [K(18 C 6)] 2[Zn(mnt) 2] bridged by K O interactions between adjacent [K(18 C 6)] + units. Complex 2 is also a one dimensional chain of [K(18 C 6)] 2[Hg(mnt) 2] bridged by K...S weak interactions between adjacent [K(18 C 6)] + and [Hg(mnt) 2] 2- .
The reactions of 18 crown 6 with each of K 2 (M = Zn, Hg; mnt = 1,2 dicyanoethene 1,2 dithiolate, C 2S 2 (CN) 2- 2) were studied and novel complexes [K ) 2 [Zn (mnt) 2] (1) and [K (18 C 6)] 2 [Hg (mnt) 2] (2) were characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. a one dimensional chain of [K (18 C 6)] 2 [Zn (mnt) 2] bridged by KO interactions between adjacent [K (18 C 6)] + units. 18 C 6] 2 [Hg (mnt) 2] bridged by K ... S weak interactions between adjacent [K (18 C 6)] + and [Hg (mnt) 2] 2-.