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本文研究了载体型钛催化剂合成高反式－１．４聚异戊二烯（ＴＰＩ）的聚合活性，初期聚合速率并对所得ＴＰＩ微观结构进行了表征。结果表明在一定范围内该催化体系催化效率较高，可达３０００ｇＴＰＩ／ｇＴｉ。聚合表观活化能为３３．５ｋＪ／ｍｏｌ，聚合速率及分子量随温度升高同时增加，合成的ＴＰＩ反式－１．４结构含量可达９８％左右
In this paper, the polymerization activity, initial polymerization rate and TP microstructure of TPI synthesized from supported titanium catalyst were investigated. The results show that within a certain range of catalytic efficiency of the catalytic system is high, up to 3000gTPI / gTi. The apparent activation energy of polymerization was 33.5kJ / mol. The polymerization rate and molecular weight increased with the increase of temperature. The content of TPI trans-1.4 was about 98%