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近年来,在有机导电高分子修饰电极的研究被大量报道的同时,无机膜(包括蒙脱土钠盐、粘土类、沸石分子筛型化合物、金属氧化物、吸附金属微粒、以及混合价态多核化合物类)修饰电极的研究亦日趋活跃,后者以过渡金属铁氰盐普鲁士蓝(PB)薄膜的研究最为重要。已有报道此类薄膜在电催化、电色显示、二次电池、及非电活性金属离子的电位或伏安测定中获
In recent years, many studies have been reported on organic conductive polymer modified electrodes. In addition, inorganic membranes (including montmorillonite sodium salts, clays, zeolite molecular sieves, metal oxides, adsorbed metal particles, and mixed valence polynuclear compounds Type) modified electrode is also increasingly active, the latter with transition metal ferricyanide Prussian blue (PB) film is the most important research. It has been reported that such films are obtained in the measurement of potential or voltammetry of electrocatalysis, electrochromic display, secondary batteries, and non-electroactive metal ions