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合成了一种新的三桥连双铁 (III)配合物 [Fe2 (IDB) 2 (O) (CH3CO2 ) 2 ]Cl2 ·CH3OH ,IDB为N ,N’ -di(2’ -benzimidazolylmethyl)imine,利用单晶X射线衍射及其它谱学方法对所合成配合物进行了表征。每个双核单元的两个铁原子均通过一个氧原子和两个醋酸根连接 ,每个铁原子同时还与位于桥氧原子对位的三齿配体IDB重脂肪链上氮原子相结合 ,每个铁 (III)中心为一变形八面体结构。对该新化合物的拉曼光谱进行了研究并对一些谱峰进行了归属
A novel triironide iron (III) complex [Fe2 (IDB) 2 (O) (CH3CO2) 2] Cl2 · CH3OH with IDB of N, N’-di (2’-benzimidazolylmethyl) The synthesized complexes were characterized by single crystal X-ray diffraction and other spectroscopic methods. Each binuclear unit of the two iron atoms are connected by an oxygen atom and two acetate, each iron atom is also located in the bridge of oxygen atoms tridentate ligand IDB heavy aliphatic chain nitrogen atoms are combined, each A center of iron (III) is a modified octahedral structure. Raman spectra of the new compounds were studied and some of the peaks were assigned