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系统研究了ＰｂＦ２＋ＧｅＯ２＋ＷＯ３ＴｍＦ３玻璃陶瓷材料中，在近红外光（１．０６μｍ）激发下，Ｔｍ３＋离子的发光特性．实验中观测到Ｔｍ３＋离子的两组峰值位置分别在２０９２０ｃｍ－１和２２１７３ｃｍ－１的蓝色上转换发光，并证实这两组上转换发光分别与吸收三个和四个光子有关，同时建立了上转换发光的模型．为了选择最佳掺杂浓度，详细地测量了Ｔｍ３＋离子峰值为２０９２０ｃｍ－１的蓝色上转换发光强度与ＴｍＦ３浓度的关系．
The luminescent properties of Tm3 + ions in PbF2 + GeO2 + WO3TmF3 glass ceramics were studied systematically under the excitation of near infrared (1.06μm). In the experiment, it was observed that the peak positions of two groups of Tm3 + ions were converted to blue at 20920 cm-1 and 22173 cm-1, respectively, and confirmed that the up-conversion luminescence of the two groups was related to the absorption of three and four photons, respectively Transform the glowing model. In order to choose the best doping concentration, the relationship between the blue upconversion luminescence and the concentration of TmF3 was measured in detail with the peak of Tm3 + at 20920 cm-1.