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自Bengough等用自由基引发聚合的方法首次得到了较高分子量的聚富马酸二乙酯后,有关富马酸酯(DRFs)类单体的聚合反应及其结构性能已进行了许多研究。结果表明,这类单体的聚合物在聚合反应活性、聚合物结构及性能等方面均有某些独特的性质,如聚富马酸二异丙酯(PDiPF)和聚富马酸二特丁酯(PDtBF)两种聚合物具有良好的氧氮透过性。我们曾研究十几种DRFs单体的聚合反应,得出非正烷基酯基的单体如富马酸二异丙酯(DiPF),富马
Many studies have been conducted on the polymerization and structural properties of fumarate (DRFs) monomers since Bengough et al. First reported the higher molecular weight poly (fumaric acid diethyl ester) by free radical initiated polymerization. The results show that the polymers of these monomers have some unique properties such as polymerization reactivity, polymer structure and properties, such as poly-fumarate (PDiPF) and polytetrafluoro fumarate Ester (PDtBF) Both polymers have good oxygen and nitrogen permeability. We have studied the polymerization of a dozen of DRFs monomers to arrive at non-n-alkyl ester-based monomers such as DiPF,