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在1673K下,通过给定化学组成的BaO-BaF2-MnO熔剂和Mn(~60%)-Fe-C(1.18%~6.40%)-P合金间的平衡实验,确定锰铁合金中碳含量的变化对磷分配比LP和锰分配比LMn的影响。结果表明,锰铁熔体中存在着一个临界碳含量[%C]*,它对应着最大的LP和最小的LMn。热力学计算表明,在本实验条件下,氧位控制环节对临界碳的存在和位置起决定性作用。而对于给定化学组成的BaO基熔剂,其相应渣系的磷酸盐容量值和锰酸盐容量值变化不大,分别为lgCP=24.80±0.15,lgCMn=9.04±0.24,它们对LP、LMn的临界转变现象影响不大。
At 1673 K, equilibrium experiments between BaO-BaF2-MnO fluxes of given chemical composition and Mn (~ 60%) - Fe-C (1.18% ~ 6.40% Effect of carbon content on phosphorus partition ratio (LP) and manganese partition ratio (LMn). The results show that there is a critical carbon content [% C] * in the ferromanganese melt, which corresponds to the maximum LP and the minimum LMn. Thermodynamic calculations show that under the experimental conditions, the control of oxygen level plays a decisive role in the existence and location of the critical carbon. For BaO-based flux with given chemical composition, the values of phosphate capacity and manganate capacity of the corresponding slag systems did not change much, which were respectively lgCP = 24.80 ± 0.15 and lgCMn = 9.04 ± 0. 24, they have little effect on the critical transition of LP and LMn.