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制备了以苯乙烯／马来酸４羧基酚酯共聚物（ Ｍ Ｅ Ｓ Ｍ Ａ）为质子供体，苯乙烯基吡啶（４ Ｓ Ｚ）为质子受体的氢键诱导液晶复合物。用 Ｄ Ｓ Ｃ和 Ｐ Ｏ Ｍ 研究二者复合前后的液晶行为。结果表明，４ Ｓ Ｚ含量在３０％ ～７０％ 的复合物表现为向列相液晶态，其中等摩尔比的复合物的热稳定性最高。并从 Ｉ Ｒ 结果讨论了 Ｍ Ｅ Ｓ Ｍ Ａ／４ Ｓ Ｚ二元组分的摩尔比与分子间氢键的关系，等摩尔比时，复合物以羧酸与吡啶环之间的氢键为主；而非等摩尔比时，存在羧酸之间的氢键。
Preparation of a styrene / maleic acid 4 carboxylate copolymer (M E S M A) as a proton donor, styrylpyridine (4 S Z) proton acceptor hydrogen bond induced liquid crystal composite . D S C and P O M were used to study the liquid crystal behavior before and after recombination. The results show that the composites with 4SZ content of 30% -70% exhibit nematic liquid crystal state, and the complexes with the same molar ratio have the highest thermal stability. And the relationship between the molar ratio of M E S M A / 4 S Z binary components and the intermolecular hydrogen bonds was discussed from the I R results. When the molar ratio is equal to the molar ratio of the carboxylic acid to the pyridine ring Dominated; instead of equimolar ratio, the presence of hydrogen bonds between carboxylic acids.