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原子光谱项是结构化学、量子化学、络合物化学教学中的难点。本文拟讨论各类电子组态原子光谱项的推求方法。主要内容有;(1)满壳层电子组态的光谱项;(2)非等价电子组态的光谱项;(3)等价电子组态的光谱项;(4)非等价电子和等价电子组态的光谱项。
Atomic spectroscopy is the structural chemistry, quantum chemistry, complex chemistry teaching difficult. This article intends to discuss the methods of deducing the atomic spectra of various electronic configurations. The main contents include: (1) Spectral terms of full shell electron configuration; (2) Spectral terms of non-equivalent electron configuration; (3) Spectral terms of equivalent electron configuration; (4) Non- Spectral terms for equivalent electronic configuration.