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前言目前,高分子化合物的合成一般通过具有特征性官能基单体的加聚、缩聚和开环聚合等方法进行。但是,现有的适宜用来合成高分子化合物的单体(具有特征性官能基的化合物)只有40—50种,并且单体的合成通常要经过复杂的途径。石油、煤焦油等化学工业的迅速发展,提供了大量来源丰富、合成方便的有机化合物。能否简化高分子化合物的合成方法,直接从一般的有机化合物经过简单的有机合成反应,来合成新的具有特殊性能的高聚物,在理论上和实践上将具有深远的意义。近十年来的研究结果确切地表明,这是完全可能的。本文选择一些主要方面,作简略的介绍。
Preface Currently, the synthesis of polymer compounds are generally carried out by methods such as addition polymerization, polycondensation and ring-opening polymerization with the characteristic functional monomer. However, there are only 40-50 kinds of monomers (compounds with characteristic functional groups) suitable for synthesizing polymer compounds, and the synthesis of monomers usually goes through complex routes. The rapid development of the chemical industry such as petroleum and coal tar provides a large number of organic compounds with abundant sources and convenient synthesis. Whether the synthesis of polymer compounds can be simplified or not, and the synthesis of new polymers with special properties directly from common organic compounds through simple organic synthesis reactions will have far-reaching theoretical and practical implications. The research results of the past decade have shown exactly that this is entirely possible. This article chooses some major aspects for a brief introduction.