Transition metal oxides as hole-transporting materials in organic semiconductor and hybrid perovskit

• 作 者: Pingli Qin Qin He Dan Ouyang Guojia Fang Wallace C.H.Choy Gang Li
• 机 构: Department of Electronic and Information Engineering,The Hong Kong Polytechnic University,School of
• 出 处: Science China(Chemistry)
• 发表日期: 2017年04期
• 关键词: perovskite transporting Transition concise attempt processed discussion recombin

Organic polymer solar cells(OSCs) and organic-inorganic hybrid perovskite solar cells(PSCs) have achieved notable progress over the past several years.A central topic in these fields is exploring electronically efficient,stable and effective hole-transporting layer(HTL) materials.The goal is to enhance hole-collection ability,reduce charge recombination,increase built-in voltage,and hence improve the performance as well as the device stability.Transition metal oxides(TMOs) semiconductors such as NiO_x,CuO_x,CrO_x,MoO_x,WO_3,and V_2O_5,have been widely used as HTLs in OSCs.These TMOs are naturally adopted into PSC as HTLs and shows their importance.There are similarities,and also differences in applying TMOs in these two types of main solution processed solar cells.This concise review is on the recent developments of transition metal oxide HTL in OSCs and PSCs.The paper starts from the discussion of the cation valence and electronic structure of the transition metal oxide materials,followed by analyzing the structure-property relationships of these HTLs,which we attempt to give a systematic introduction about the influences of their cation valence,electronic structure,work function and film property on device performance.

Organic polymer solar cells (OSCs) and organic-inorganic hybrid perovskite solar cells (PSCs) have achieved notable progress over the past several years. A central topic in these fields is exploring electronically efficient, stable and effective hole-transporting layer (HTL) materials The goal is to enhance hole-collection ability, reduce charge recombination, increase built-in voltage, and hence improve the performance as well as the device stability. Transition metal oxides (TMOs) semiconductors such as NiO_x, CuO_x, CrO_x, MoO_x, These TMOs are naturally adopted into PSC as HTLs and shows their importance. There are similarities, and also differences in applying TMOs in these two types of main solution processed solar cells. concise review is on the recent developments of transition metal oxide HTL in OSCs and PSCs. The paper starts from the discussion of the cation valence and electronic structure of the transition metal oxide materials, foll owed by analyzing the structure-property relationships of these HTLs, which we attempt to give a systematic introduction about the influences of their cation valence, electronic structure, work function and film property on device performance.