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这一短文报告了我们关于最大重迭法与杂化轨道的部分工作。按照这一方法和键强的概念.在ML_k型分子中.第个j的键强F_j等于配体L_j的轨道ω_j与中心原子M的相应的杂化轨道ψ_j之间的重迭积分,即F_j=<ω_jψ_j> 在K=2和取键轨道角度部分的投影近似后.根据本文的普适性处理.可以得到与唐敖庆和Pauling完全一致的公式。本文对于随意任取ι值(角量子数)时键强度、键角和轨道特性的关系作了推广.还导出了含g和h轨道的两个新公式。
This essay reports on some of our work on the law of maximum overlap and the hybrid orbit. According to this method and the concept of strong bonds, in the molecule ML_k, the bond strength F_j of the jth bond is equal to the overlap integral between the orbit ω_j of the ligand L_j and the corresponding hybrid orbit ψ_j of the central atom M, that is, F_j = <ω_jψ_j> After the projection of K = 2 and the key orbital angle is approximated, we can get the exact formula which is consistent with Tang Ao-Qing and Pauling according to the universal treatment in this paper. In this paper, the relationship between the bond strength, bond angle and orbit properties is arbitrarily arbitrarily taken as the value of ι (the number of angles), and two new formulas with g and h orbits are also derived.