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由于胶束增溶三元络合物的应用日益增长,表面活性剂作用机理的研究显得越来越重要了。人们在这领域已进行了许多研究,如西田宏的拟均相萃取理论;小原人司的电荷集合体电场吸附模型;萨文的单分子作用理论等等。尤其值得注意的是慈云祥等最近提出的协同微扰理论,认为金属离子和表面活性剂作为两个电场,从铬天青S分子两端靠近,对铬天青S分子产生协同微扰,从而造成铬天青S分子完全去质子化。
Due to the increasing application of micellar solubilizing ternary complexes, the study on the mechanism of action of surfactants has become more and more important. Many researches have been carried out in this field, such as the pseudo-homogeneous extraction theory of Nishida Hiroshi, the charge-collector electric field adsorption model of Minyahara Division, Sarvan’s theory of single-molecule action and so on. Of particular note is the recently proposed Cooperative Perturbation Theory of Ciyunxiang et al. That metal ions and surfactants act as two electric fields, both ends of which are close to chrome azurol S molecules, which cause synergistic perturbation to chrome azurol S molecules, As a result, the chrome azurol S molecule completely deprotonated.