Azomethine-ylides from ninhydrin in reactions with cyclopropenes

来源 :中国化学会第十六届全国有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户：newAya

【摘要】

：

　　In continuation of our work on the interaction of 1,2-diphenylcyclopropenes with stabilized azomethine-ylides generated in situ from ninhydrin1,isatin2,11H-

【作者】

：

Siqi Wang Stanislav I.Selivanov Alexander V.Stepakov

【机构】

：

InstituteofChemistry,Saint-PetersburgStateUniversity,Saint-Petersburg,Russia,198504

【出处】

：

中国化学会第十六届全国有机合成化学学术研讨会

【发表日期】

：

2019年8期

【关键词】

：

azomethine-ylide cyclopropenes stereoselectivity azabicyclo[3.1.0]hexane

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　　In continuation of our work on the interaction of 1,2-diphenylcyclopropenes with stabilized azomethine-ylides generated in situ from ninhydrin1,isatin2,11H-indeno[1,2-b]quinoxaline-11-one3 and amines,we investigated reactions of variously substituted cyclopropenes 1a-e with azomethine-ylide(the product of ninhydrin 2 and primary α-amino acids 3 condensation)or with spiro-aziridine 5(the product of ninhydrin and sarcosine condensation).

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Azomethine-ylides from ninhydrin in reactions with cyclopropenes

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