Transfer Hydrogenation and Deoxygenation with Novel Iridium Catalysts

• 作 者: Zhanhui Yang
• 机 构: DepartmentofOrganicChemistry,SchoolofChemistry,BeijingUniversityofChemicalTechnology,Beijing100029
• 出 处: 中国化学会第十六届全国有机合成化学学术研讨会
• 发表日期: 2019年8期
• 关键词: transfer hydrogenation deoxygenation iridium catalysis water solvent

　　We have developed a new type of iridium catalysts.In the presence of formic acid,the catalysts are used to highly chemoselectively and efficiently reduce aldehydes 1 and ketones,2 with S/C ratios as high as 100,000.