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基于前期在硫元素介导的烯丙位、炔丙位碳氢键官能化反应领域的积累[1]，我们开发了一种炔烃双官能化反应(图1)[2]。该反应适用于氮、氧、硫、卤素及多种两可亲核试剂，可实现从苯基取代的内炔烃到多种α-杂原子取代的酮或相应杂环产物的一锅法高效转化。
炔烃双官能化制备α-杂原子取代的酮
【摘 要】
：
基于前期在硫元素介导的烯丙位、炔丙位碳氢键官能化反应领域的积累[1]，我们开发了一种炔烃双官能化反应(图1)[2]。该反应适用于氮、氧、硫、卤素及多种两可亲核试剂，可实
【机 构】
：
北京化工大学北京100029
【出 处】
：
中国化学会第十六届全国有机合成化学学术研讨会
【发表日期】
：
2019年8期
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