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In this study,poly(ethylene terephthalate)(PET)/ poly(ethylene glycol)(PEG)composite fibrous mats were fabricated by electrospinning mixed PET/PEG solutions with different mixing ratios.And then the composite mats were dipped into 75 ℃ hot water in order to remove the PEG for 24 h and form multi-porous structure.SEM imaging indicated that the multi-porous structure of PET mats was achieved after removing PEG.