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As a typical conductive polymer,polyaniline(PANI)has successfully wrapped on multiwalled carbon nanotube(MWCNT)film via in situ polymerization.The polyaniline/multiwalled carbon nanotube(PANI/MWCNT)composites,which can combine the excellent conducting and mechanical properties of MWCNT and high pseudocapacitance property of PANI,represent an important breakthrough for developing a new generation of electrochemical energy storage devices.In this work,we successfully prepared a series of hybrid materials by changing the concentration of aniline monomer.