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Highly oriented <111> and <110> β-SiC films were prepared on Si(100)single crystal substrates by laser chemical vapor deposition using a diode laser(wavelength = 808 nm)and HMDS(Si(CH3)3-Si(CH3)3)as a precursor.The effects of laser power(PL),total pressure(Ptot),and deposition temperature(Tdep)on the orientation,microstructure and deposition rate(Rdep)were investigated.The orientation of the β-SiC films changed from <111> to random to <110> with increasing PL and Ptot.