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In this study,the(Mn,Sb)co-doped PbCa0.01[(MnxZn0.1-x)1/3(SbxNb0.1-x)2/3(Zr0.505Ti0.4895)0.9]O3(PCZMNS-PZT-100x)ceramics were prepared near the morphotropic phase boundary(MPB)using the wolframite precursor method.The phase structure evolutions,electrical,and temperature stability properties are systematically investigated.As the fraction of rhombohedral phase increases,the degree of disorder in the diffused phase transition(DPT)correspondingly increases.