Intramolecularenantiomerism in S(+)2,2-dimethyl-1,3-Dioxolane-4-methanol The interpretation of Raman

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【摘要】

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A bond polarizability algorithm is developed and applied to interpret the Raman optical activity (ROA) intensity.It is demonstrated that for the chiral molecule

【作者】

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吴国祯王培杰

【机构】

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清华大学物理系,低维量子物理国家重点实验室,北京清华园100084首都师范大学物理系,北京市纳米光电子学重点实验室,北京100048

【出处】

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第十八届全国光散射学术会议

【发表日期】

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2015年10期

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A bond polarizability algorithm is developed and applied to interpret the Raman optical activity (ROA) intensity.It is demonstrated that for the chiral molecule such as S(+)2, 2-dimethyl-1, 3-dioxolane-4-methanol, there exists approximate (or symmetry breaking) mirror reflection that reverses the signs of the differential bond polarizabilities of the pair bond coordinates that are related to each other by the mirror reflection, just like that between the right and left enantiomers.

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Intramolecularenantiomerism in S(+)2,2-dimethyl-1,3-Dioxolane-4-methanol The interpretation of Raman

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