【摘 要】
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The high temperature chloridizing roasting is one of useful methods to separate nonferrous metals from pyrite cinder and metallurgy slag.However, as one kind of main nonferrous metals in pyrite cinder
【机 构】
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School of Iron and Steel,Soochow University,178 Ganjiang East Road,Suzhou 215021,China
【出 处】
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The 6th International Conference on Hydrometallurgy(第六届国际湿法冶
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The high temperature chloridizing roasting is one of useful methods to separate nonferrous metals from pyrite cinder and metallurgy slag.However, as one kind of main nonferrous metals in pyrite cinder and metallurgy slag, the occurrence of lead is complicated and its chlorination behavior is not demonstrated.In the present study, chlorination behaviors ofPbO, PbS and PbSiO3 at the temperature range of 1025-1175C in air by simulating the chloridizing roasting process of pyrite cinder have been investigated.This study found that it is easier to remove PbS and PbO than PbSiO3.If enough chloride additives were added, the differences of Pb removal rates among PbO, PbS and PbSiO3 would disappear.In addition, the presence of CaO dramatically increases Pb removal.SiO2 influences the Pb removal positively from PbSiO3 and negatively from PbO.A small amount of A12O3 has almost no effect of Pb removal from PbO and PbSiO3, but the high dosage of A12O3 dccrcases Pb removal from them.In addition, a small amount of MgO favors to Pb removal while the high dosage of MgO harm to Pb removal.Fe3O4 influences the Pb removal rate from PbO and PbSiO3 positively.
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