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This study investigated the effect of additions, P2O5 and B2O3, on the properties, including viscosity and crystallization behaviors of Ti-bearing blast furnace (Ti-BF) slags with the purpose of Ti extraction using selective crystallization and phase separation (SCPS) method.The investigation of the crystallization behaviors were performed using a single hot thermocouple technique (SHTT) and the viscosity was obtained by rotating cylinder method.