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This paper summarized the research works related to the electro-spinning technology and principles. A detailed analysis is conducted on the electrochromie mechanism of the polyaniline composites, the characterization of the polyaniline superfine fiber is provided for the analysis of polyaniline composites. Prospects through electro-spinning polyaniline composite fiber have been made to improve the microstructure and electrical conductivity and mechanical properties, so as to improve its electrochromie properties.