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New ionic liquid-modified polymer sorbents were developed by the surface chemical modification of the polymer using synthesized ionic liquids.The obtained ionic liquid-modified particles were successfully used as a special sorbent in solid-phase extraction process to isolate the caffeine and theophyiline from tea.Different washing and elution solvents such as water,acetonitrile,and acetonitrile-acetic acid (90/10,v/v) were evaluated.By comparing the results of different cartridges with blank polymer,traditional C18 and ionic liquid-modified polymer,higher recovery was observed on the ionic liquid-modified polymer sorbents.A quantitative analysis was conducted by high-performance liquid chromatography using a C18 colunm (5 μm,150×4.6 mm).