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Aerosol has significant effects on direct/indirect climate forcing, visibility, tropospheric chemistry and human health.Water can represent an extensive proportion of the mass of aerosol particles, and can also serve as a medium for aqueous—phase reactions in such particulate matter.In this study, a new method is proposed to estimate the aerosol liquid water content at high relative humidity, based on aerosol hygroscopic growth factors, particle number size distribution and relative humidity measured during the Haze in China (HaChi) campaign of July— August, 2009.