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A novel polymer-nanoclay hybrid nanocomposite based on polyvinyl acetate (PVAc)-organophilic montmorillonite (OMMT) has been reported via an in situ intercalated polymerization technique.The hybrid material was synthesized by one-step emulsion polymerization of vinyl acetate (VAc) in the presence of OMMT using polyvinyl alcohol (PVA) as the stabilizing agent.The intercalated polymerization was characterized by X-ray diffraction (XRD).