【摘 要】
：
Nanoscale ionic materials (NIMs) are novel organic-inorganic hybrid materials consisting of multi-charged inorganic nanocore that is electrostatically coupled by oppositely charged organic canopy [1].
【机 构】
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School of Chemistry and Biological Engineering,University of Science and Technology Beijing,Beijing
【出 处】
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Seventh International Symposium On Engineering Plastics (第七届
论文部分内容阅读
Nanoscale ionic materials (NIMs) are novel organic-inorganic hybrid materials consisting of multi-charged inorganic nanocore that is electrostatically coupled by oppositely charged organic canopy [1].The out-shell canopy is commonly mono-functionalized, thus one canopy molecule can just interact with one oppositely charged point of nanocores.Here, we partially replaced the mono-functionalized canopy with the bi-functionalized ones, and therefore obtained the novel NIMs with 3-D supramolecular ionic network that showed the self-healing behavior under the large-amplitude oscillatory shear (LAOS) flow [2], which was unavailable for the NIMs with mono-functionalized canopy.
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