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Porphyrin and diporphyrin dyes with a push-pull framework have been prepared and used in dye-sensitized solar cells (DSSC), Their spectral, electrochemical and photovoltaic properties were investigated.The photovoltaic measurements show that YD2-o-C8 achieves a record power conversion efficiency ~12% using Co(Ⅱ)/Co(Ⅲ) as the electrolyte.