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Polymer-supported ionic liquids (PSILs) were prepared via covalent anchoring ofimidazolium salts onto Merrifield resin and characterized by FT-IR, TGA and elementary analysis.PSILs were firstly examined for the supports of solvent-impregnated resin (SIR),which have tunable properties, such as hydrophilicity/hydrophobicity, polarity, thermal and acid stability.The stabilities of SIRs based on polymer-supported imidazolium chloride (RCl) and imidazolium hexafluorophosphate (RPF6) with Cyanex 923 extractant and [Csmim][PF6] were evaluated.