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作者曾根据苏联学者G.I.Golodets对含分子氧的多相催化反应的精辟论述,将烯烃选择氧化的幂型速度方程按Redox机理作了解释。随着研究工作的深入和扩展,发现复合氧化物催化剂上烯烃氧化反应的动力学表征存在着一定的规律性。本文试图对这些规律性进行总结和说明。
The author has based on the Soviet Union scholar G.I.Golodets molecular oxygen containing heterogeneous catalytic reaction of the brilliant discussion of the selective oxidation of olefin power rate equation Redox mechanism is explained. With the deepening and expansion of the research work, it has been found that the kinetic characterization of the olefin oxidation on the composite oxide catalyst has certain regularity. This article attempts to summarize and explain these regularities.