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5-叔丁基-1,3-间苯二甲酸、1,3-双吡啶丙烷与醋酸镍以1∶1∶1的摩尔比在纯水溶剂中反应合成了镍的配合物{[Ni2(L)2(1,3-dpp)2(H2O)]·H2L}n(H2L=5-tert-butylisophthalic acid,1,3-dpp=1,3-di(4-pyridyl)propane).通过红外以及X-衍射分析,确认了其化学结构.Mr=1112.02,晶体属单斜晶系,C2/m空间群,晶胞参数:a=35.166(4),b=20.051(2),c=17.115(2),β=95.003(2)°,V=12022(3)3,Z=8,Dc=1.229mg/m3,最终偏差因子R1=0.0720,wR2=0.1901[I>2σ(I)].
5-tert-butyl-1,3-isophthalic acid, 1,3-bispyridine propane and nickel acetate in a pure water solvent at a molar ratio of 1: 1: 1 to synthesize a nickel complex {[Ni2 (H2L = 5-tert-butylisophthalic acid, 1,3-dpp = 1,3-di (4-pyridyl) propane) And the X-ray diffraction analysis confirmed the chemical structure of the crystal. The crystal structure of the crystal is monoclinic and C2 / m space group with a = 35.166 (4) and b = 20.051 (2) , c = 17.115 (2) β, β = 95.003 (2) °, V = 12022 (3) 3, Z = 8, Dc = 1.229mg / m3 and the final deviation factor R1 = 0.0720, wR2 = 0.1901 [I> 2σ I)].