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环糊精分子结构上的特点使其在诸多领域有广泛的应用,其中环糊精在聚合反应中的应用正引起广泛关注,已逐渐成为高分子科学研究的重要领域。环糊精不但可以用于形成超分子聚合物,而且可以用于单体分子的聚合反应中。环糊精在聚合反应中不但可以担当单体、引发剂、模板,同时,还起到增溶、分子伴侣、反应活性调控、改变聚合物性质等作用。本文综述了近年来环糊精及其衍生物在聚合物合成过程中应用的研究进展,着重介绍了环糊精在合成聚合物中所起到的不同作用、应用原理等方面的研究成果,并对此领域的未来发展做了展望。
The molecular structure of cyclodextrin has made it widely used in many fields. Among them, the application of cyclodextrin in polymerization has drawn wide attention and has gradually become an important field of polymer science research. Cyclodextrins can be used not only for the formation of supramolecular polymers, but also for the polymerization of monomeric molecules. Cyclodextrin can not only act as monomers, initiators and templates in the polymerization, but also act as solubilizers, molecular chaperones, regulating the activity and changing the properties of polymers. In this paper, the recent advances in the application of cyclodextrins and their derivatives in polymer synthesis are reviewed. The different effects and application principles of cyclodextrins in synthetic polymers are reviewed. The future development of this area is prospected.