论文部分内容阅读
过渡金属的双亚砜配合物已有一些综述,多数是内、外消旋两种混合异构体的配合物.本文讨论的内、外消旋双亚砜的镧系元素配合物,至今报道极少,我们合成的Nd(Ⅲ)的内、外消旋双(正辛基亚砜)乙烷配合物尚未见报道. 实验仪器 DuPont1090热分析仪,DDS-11型电导率仪,FT-5-DX红外光谱仪,Niciet FTIR 170XS型(25000～10cm~(-1))红外光谱仪,Backmann Du-8B可见紫外光谱仪,D/MAX-IIIA X射线衍射仪.
There are some reviews about the transition metal sulfoxides, most of them are the complexes of the two isomers of racemic and racemic racemates. The lanthanide complexes of racemic and disulfided sulfones discussed in this paper have been reported so far Few, our synthesis of Nd (Ⅲ), racemic bis (n-octyl sulfoxide) ethane complex has not been reported.Experimental instruments DuPont1090 thermal analyzer, DDS-11 conductivity meter, FT-5 -DX infrared spectrometer, Niciet FTIR 170XS (25000 ~ 10cm -1) infrared spectrometer, Backmann Du-8B visible ultraviolet spectrometer, D / MAX-IIIA X-ray diffractometer.