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Silicon is an indirect semiconductor with a band-gap of 1.11 eV.Therefore,there isno optical recombination in bulk silicon in the visible region.Porous silicon(PS)preparedby anodic oxidation at constant current density in HF solution has aroused great researchinterest since Canham reported its strong visible photoluminescence(PL)at roomtemperature in 1990.Many experimental results indicated that PL of PS is mainlyattributed to the quantum confinement effect(QCE)in PS layer.Unlike the lay-
Silicon is an indirect semiconductor with a band-gap of 1.11 eV.Therefore, there is no optical recombination in bulk silicon in the visible region. Porous silicon (PS) preparedby anodic oxidation at constant current density in HF solution has aroused great research interest since Canham reported Its strong visible photoluminescence (PL) at room temperature in 1990. Many experimental results indicated that PL of PS is mainlyattributed to the quantum confinement effect (QCE) in PS layer .Unlike the lay-