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Hayden和O′Connell利用非极性偏心因子ω′作为第三参数关联第二维里系数,取得了较高的汽相拟合精度。ω′的定义为:
Hayden and O’Connell used the non-polar eccentricity ω ’as the third parameter to correlate the second virial coefficient, and achieved a high vapor-phase fitting accuracy. ω ’is defined as: